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Li, L.; Shao, S.; Li, D.; Yang, W.; Yin, X.; Zhang, Y.; Chen, Y.; Liu, Y.
Desalination 535: 115804
2022
ISSN/ISBN: 0011-9164 Accession:098940067Article/Abstract emailed within 1 workday
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Summary
A green fluorescent labeled scale inhibitor, curcumin-poly (malic acid) (Cur-PMA) was synthesized from curcumin and malic acid (MA). The structure of Cur-PMA was characterized by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (1H NMR) and gel permeation chromatography (GPC) analysis. Thermogravimetric analysis (TGA) and fluorescence spectroscopy revealed that Cur-PMA had good thermal stability and was expected to enable on-line detection. The static scale inhibition experiment showed that the scale inhibition rate of Cur-PMA on calcium sulfate can reach 100% with 10 mg/L. In addition, the impacts of pH and environmental temperature on calcium sulfate scale were discussed. The influence on formation of CaSO4 was evaluated with combination of scanning electronic microscopy (SEM), X-ray powder diffraction (XRD) and Molecular dynamics (MD) simulation. It was shown that the scale inhibition ability of Cur-PMA molecules was mainly through adsorption on the surface of growing crystals to inhibit the growth of these crystal planes.References
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